云南富盛铅锌矿床闪锌矿硫、铅、锌、镉同位素特征及其指示意义Characteristics of sulfur, lead, zinc and cadmium isotopes of sphalerites in the Fusheng Pb-Zn deposit in Yunnan Province and their indicative significances
许冲;钟宏;朱维光;唐亮;宋长顺;罗光杰;
摘要(Abstract):
富盛铅锌矿床位于川滇黔铅锌矿集区东南部,与富乐铅锌矿床(大型)邻近。矿体赋存于下二叠统茅口组(P_1m)白云质灰岩或白云岩中,矿体形态为似层状和透镜状。矿物组合简单,主要为闪锌矿、方铅矿、黄铁矿、方解石和白云石。矿石构造主要为角砾状、块状、浸染状和脉状构造,矿石结构以半自形-自形粒状结构和半自形-他形粒状结构为主。富盛铅锌矿床的硫化物(方铅矿、闪锌矿)矿物的δ(34)S值变化范围为+9.2‰~+15.9‰;闪锌矿单矿物的(34)S值变化范围为+9.2‰~+15.9‰;闪锌矿单矿物的(206)Pb/(206)Pb/(204)Pb、(204)Pb、(207)Pb/(207)Pb/(204)Pb和(204)Pb和(208)Pb/(208)Pb/(204)Pb组成范围分别为:18.5637~18.6078、15.6887~15.6939和38.563~38.586;闪锌矿单矿物δ(204)Pb组成范围分别为:18.5637~18.6078、15.6887~15.6939和38.563~38.586;闪锌矿单矿物δ(66)Zn和δ(66)Zn和δ(114)Cd值变化范围分别为:+0.09‰~+0.33‰和+0.07‰~+0.53‰。结合前人研究成果,本文得出以下结论:1)富盛铅锌矿床的硫主要来源于沉积地层中的蒸发岩或海水硫酸盐岩的热化学还原作用;2)富盛铅锌矿床的铅和锌主要来源于元古界基底地层,但不排除有少部分锌来源于震旦系-二叠系地层沉积岩;3)富盛铅锌矿床应属于MVT铅锌矿床,其矿床成因及成矿模式均可对比MVT铅锌矿床来解释。
关键词(KeyWords): 富盛铅锌矿床;S-Pb-Zn-Cd同位素;成矿物质来源;川滇黔铅锌矿集区
基金项目(Foundation): 贵州省基础研究计划项目(编号:黔科合基础-ZK[2022]一般336);; 贵州师范学院博士项目(编号:校2021009)
作者(Authors): 许冲;钟宏;朱维光;唐亮;宋长顺;罗光杰;
DOI: 10.16461/j.cnki.1000-4734.2022.42.095
参考文献(References):
- [1]吕豫辉,韩润生,任涛,等.滇东北矿集区云南富乐厂铅锌矿区断裂构造控矿特征及其与成矿的关系[J].现代地质,2015,29(3):563-575.
- [2]吕召俊.云南富源县富盛铅锌矿特征及构造控矿因素[J].云南地质,2019,38(4):426-430.
- [3]洪明春,朱勋帅,李华明.云南富源县富盛铅锌矿地质特征及成因浅析[J].世界有色金属,2020(4):109+111.
- [4]马美娟.滇东北富乐厂铅锌矿床地球化学及找矿方向研究[D].昆明理工大学,2015.
- [5]李珍立.云南富乐铅锌矿床成矿地质地球化学及找矿方向[D].贵阳:中国科学院地球化学研究所,2016.
- [6]司荣军.云南省富乐分散元素多金属矿床地球化学研究[D].贵阳:中国科学院地球化学研究所,2005.
- [7]MARéCHAL C N,TéLOUK P,ALBARèDE F.Precise analysis of copper and zinc isotopic compositions by plasma-source mass spectrometry[J].Chem Geol,1999,156:251-273.
- [8]WEN H J,ZHU C W,ZHANG Y X,et al.Zn/Cd ratios and cadmium isotope evidence for the classification of lead-zinc deposits[J].Sci Rep,2016,6(1):25273.
- [9]ROBINSON B W,KUSAKABE M.Quantitative preparation of sulfur dioxide for 32S/34S analyses from sulfides by combustion with cuprous oxide[J].Anal Chem,1975,47(7):1179-1181.
- [10]ZHU C W,WEN H J,ZHANG Y X,et al.Cadmium and sulfur isotopic compositions of the Tianbaoshan Zn-Pb-Cd deposit,Sichuan Province,China[J].Ore Geol Rev,2016,76:152-162.
- [11]BELSHAW N S,FREEDMAN P A,O’NIONS R K,et al.A new variable dispersion double-focusing plasma mass spectrometer with performance illustrated for Pb isotopes[J].Int.J.Mass Spectrom,1998,181:51-58.
- [12]ZHOU J X,GAO J G,CHEN D,et al.Ore genesis of the Tianbaoshan carbonate hosted Pb-Zn deposit,Southwest China:geologic and isotopic(C-H-O-S-Pb) evidence[J].Int Geol Rev,2013,55:1300-1310.
- [13]ZHOU J X,HUANG Z L,BAO G P.Geological and sulfur-lead-strontium isotopic studies of the Shaojiwan Pb-Zn deposit,southwest China:implications for the origin of hydrothermal fluids[J].J Geochem Explor,2013,128:51-61.
- [14]ZHOU J X,HUANG Z L,YAN Z F.The origin of the Maozu carbonate-hosted Pb-Zn deposit,southwest China:constrained by C-O-S-Pb isotopic compositions and Sm-Nd isotopic age[J].J Asian Earth Sci,2013,73:39-47.
- [15]ZHOU J X,HUANG Z L,ZHOU M F,et al.Constraints of C-O-S-Pb isotope compositions and Rb-Sr isotopic age on the origin of the Tianqiao carbonate-hosted Pb-Zn deposit,SW China[J].Ore Geol Rev,2013,53:77-92.
- [16]GAO Z F,ZHU X K,SUN J,et al.Spatial evolution of Zn-Fe-Pb isotopes of sphalerite within a single ore body:A case study from the Dongshengmiao ore deposit,Inner Mongolia,China[J].Miner Deposita,2018,53:55-65.
- [17]唐索寒,朱祥坤,李津,等.用于多接收器等离子体质谱测定的铁铜锌同位素标准溶液研制[J].岩矿测试,2016,35(2):127-133.
- [18]ABOUCHAMI W,GALER S J G,HORNER T J,et al.A common reference material for cadmium isotope studies-NIST SRM 3108[J].Geostand Geoanal Res,2013,37(1):5-17.
- [19]ZHANG Y X,WEN H J,ZHU C W,et al.Cd isotope fractionation during simulated and natural weathering[J].Environ Pollut,2016,216:9-17.
- [20]许冲.硫、铅、锌、镉同位素对川滇地区铅锌矿床成矿物质来源及运移的指示[D].贵阳:中国科学院地球化学研究所,2019.
- [21]崔银亮,周家喜,黄智龙,等.云南富乐铅锌矿床地质、地球化学及成因[J].岩石学报,2018,34(1):194-206.
- [22]OHMOTO H.Systematics of sulfur and carbon isotopes in hydrothermal ore deposits[J].Econ Geol,1972,67(5):551-579.
- [23]OHMOTO H,GOLDHABER M B.Sulfur and carbon isotopes[M]//Barnes H L.Geochemistry of Hydrothermal Ore Deposits.third ed.New York:Wiley,1997:517-611.
- [24]OHMOTO H,RYE R O.Isotopes of sulfur and carbon[J].Geochemistry of hydrothermal ore deposits,1979:509-567.
- [25]SEAL R R.Sulfur isotope geochemistry of sulfide minerals[J].Rev Mineral Geochem,2006,61:633-677.
- [26]CLAYTON R N.Isotopic thermometry[M]//Newton RC,et al.Thermodynamics of Minerals and Melts.New York:Speinger Verlag,1981:85-109.
- [27]任涛,周家喜,王蝶,等.滇东北富乐铅锌矿床微量元素和S-Pb同位素地球化学研究[J].岩石学报,2019,35(11):3493-3505.
- [28]CHAUSSIDON M,ALBARèDE F,SHEPPARD S M F.Sulphur isotope variations in the mantle from ion microprobe analyses of microsulphide inclusions[J].Earth and Planetary Science Letters,1989,92(2):144-156.
- [29]黄智龙,陈进,韩润生,等.云南会泽超大型铅锌矿床地球化学及成因-兼论峨眉山玄武岩与铅锌成矿的关系[M].北京:地质出版社,2004.
- [30]CLAYPOOL G E,HOLSER W T,KAPLAN I R,et al.The age curves of sulfur and oxygen isotopes in marine sulfate and their mutual interpretation[J].Chem Geol,1980,28:199-260.
- [31]柳贺昌,林文达.滇东北铅锌银矿床规律研究[M].昆明:云南大学出版社,1999:184-196.
- [32]OHMOTO H.Stable isotope geochemistry of ore deposits[J].Reviews in Mineralogy and Geochemistry,1986,16(1):491-559.
- [33]JORGENSEN B B,ISAKSEN M F,JANNASCH H W.Bacterial sulfate reduction above 100℃in deep-sea hydrothermal vent sediments[J].Science,1992,258(5089):1756-1757.
- [34]OHMOTO HIROSHI,KAISER C J,GEER K A.Systematics of sulphur isotopes in recent marine sediments and ancient sediment-hosted base metal deposits[J].Stable isotopes and fluid processes in mineralization,1990,23:70-120.
- [35]BASUKI N I,TAYLOR B E,SPOONER E T C.Sulfur isotope evidence for thermochemical reduction of dissolved sulfate in Mississippi Valley type zinc-lead mineralization,Bongara area,northern Peru[J].Econ Geol,2008,103(4):783-799
- [36]ZHOU J X,HUANG Z L,GAO J G,et al.Geological and C-O-S-Pb-Sr isotopic constraints on the origin of the Qingshan carbonate-hosted Pb-Zn deposit,SW China[J].Int Geol Rev,2013,55:904-916.
- [37]ZHENG M H,WANG X C.Genesis of the Daliangzi Pb-Zn deposit in Sichuan,China[J].Econ Geol,1991,86(4):831-846.
- [38]WU T,HUANG Z L,HE Y F,et al.Metal source and ore-forming process of the Maoping carbonate-hosted Pb-Zn deposit in Yunnan,SW China:Evidence from deposit geology and sphalerite Pb-Zn-Cd isotopes[J].Ore Geol Rev,2021,135(36):104214.
- [39]涂光炽,高振敏,胡瑞忠,等.分散元素地球化学及成矿机制[M].北京:地质出版社,2004.
- [40]ZHU C W,WEN H J,ZHANG Y X,et al.Characteristics of Cd isotopic compositions and their genetic significance in the lead-zinc deposits of SWChina[J].Sci China Earth Sci,2013,56(12):2056-2065.
- [41]SCHWARTZ M O.Cadmium in zinc deposits:economic geology of a polluting element[J].Int Geol Rev,2000,42(5):445-469.
- [42]YANG J L,LI Y B,LIU S Q,et al.Theoretical calculations of Cd isotope fractionation in hydrothermal fluids[J].Chem Geol,2015,391:74-82.
- [43]ZHU C W,WEN H J,ZHANG Y X,et al.Isotopic geochemistry of cadmium:a review[J].Acta Geol Sin Engl,2015,89(6):2048-2057.
- [44]WILKINSON J J,WEISS D,MASON T,et al.Zinc isotope variation in hydrothermal systems:preliminary evidence from the Irish Midlands ore field[J].Econ Geol,2005,100(3):583-590.
- [45]ZHOU J X,HUANG Z L,LV Z C,et al.Geology,isotope geochemistry and ore genesis of the Shanshulin carbonate-hosted Pb-Zn deposit,southwest China[J].Ore Geol Rev,2014,63:209-225.
- [46]ZHOU J X,HUANG Z L,ZHOU M F,et al.Zinc,sulfur and lead isotopic variations in carbonate-hosted Pb-Zn sulfide deposits,southwest China[J].Ore Geol Rev,2014,58:41-54.
- [47]MASON T F,WEISS D J,CHAPMAN J B,et al.Zn and Cu isotopic variability in the Alexand rinka volcanic-hosted massive sulfide (VHMS) ore deposit,Urals,Russia[J].Chem Geol,2005,221:170-187.
- [48]JOHN S,ROUXEL O,CRADDOCK P,et al.Zinc stable isotopes in seafloor hydrothermal vent fluids and chimneys[J].Earth Planet Sci Lett,2007,269(1):17-28.
- [49]TOUTAIN J P,SONKE J,MUNOZ M,et al.Evidence for Zn isotopic fractionation at Merapi volcano[J].Chem Geol,2008,253:74-82.
- [50]KELLEY K D,WILKINSON J J,CHAPMAN J B,et al.Zinc isotopes in sphalerite from base metal deposits in the Red Dog district,Northern Alaska[J].Econ Geol,2009,104(6):767-773.
- [51]GAGNEVIN D,BOYCE A J,BARRIE C D,et al.Zn,Fe and S isotope fractionation in a large hydrothermal system[J].Geochim Cosmochim Acta,2012,88:183-198.
- [52]XU C,ZHONG H,HU R Z,et al.Sources and ore-forming fluid pathways of carbonate-hosted Pb-Zn deposits in Southwest China:implications of Pb-Zn-S-Cd isotopic compositions[J].Miner Deposita,2020,55(3):491-513.
- [53]SIVRY Y,RIOTTE J,SONKE J,et al.Zn isotopes as tracers of anthropogenic pollution from Zn-ore smelters the Riou Mort-Lot river system[J].Chem Geol,2008,255(3):295-304.
- [54]DEKOV V M,CUADROS J,KAMENOV G D.Metalliferous sediments from the HMS Challenger voyage (1872-1876)[J].Geochim Cosmochim Acta,2010,74(17):5019-5038.
- [55]何承真,肖朝益,温汉捷,等.四川天宝山铅锌矿床的锌-硫同位素组成及成矿物质来源[J].岩石学报:2016,32(11):3394-3406.
- [56]何承真.四川天宝山铅锌矿床的锌-硫同位素组成及成矿物质来源[D].贵阳:中国科学院地球化学研究所,2017.
- [57]MARéCHAL C N,NICOLAS E,DOUCHET C,et al.Abundance of zinc isotopes as a marine biogeochemical tracer[J].Geochem Geophys Geosyst,2000,1(5).
- [58]LITTLE S H,VANCE D,MCMANUS J,et al.Key role of continental margin sediments in the oceanic mass balance of Zn and Zn isotopes[J].Geol,2016,44(4):207-210.
- [59]LV Y W,LIU S A,ZHU J M,et al.Copper and zinc isotope fractionation during deposition and weathering of highly metalliferous black shales in Central China[J].Chem Geol,2016,445:24-35.
- [60]CHEN H,SAVAGE P S,TENG F Z,et al.Zinc isotope fractionation during magmatic differentiation and the isotopic composition of the bulk Earth[J].Earth Planet Sci Lett,2013,369:34-42.
- [61]PICHAT S,DOUCHET C,ALBARèDE F.Zinc isotope variations in deep-sea carbonates from the eastern equatorial Pacific over the last 175 ka[J].Earth Planet Sci Lett,2003,210(1):167-178.
- [62]DUAN J L,TANG J X,LIN B.Zinc and lead isotope signatures of the Zhaxikang Pb-Zn deposit,South Tibet:Implications for the source of the ore-forming metals[J].Ore Geol Rev,2016,78:58-68.
- [63]LI X H,WANG J Q,CHU F Y,et al.Zn isotopes in hydrothermal sulfides and their oxidation products along the south mid-Atlantic ridge:evidence of hydrothermal fluid deposition[J].Geo-Mar Lett,2018,38(2):131-138.
- [64]蒋少涌,陆建军,顾连兴,等.多接收电感耦合等离子体质谱(MC-ICPMS)测量铜、锌、铁的同位素组成及其地质意义[J].矿物岩石地球化学通报,2001,4:431-433.
- [65]ALBARèDE F.The stable isotope geochemistry of copper and zinc[J].Rev Mineral Geochem,2004,55:409-427.
- [66]PA?AVA J,TORNOS F,CHRASTNYV.Zinc and sulfur isotope variation in sphalerite from carbonate-hosted zinc deposits,Cantabria,Spain[J].Mineralium Deposita,2014,49(7):797-807.
- [67]ZHOU J X,LUO K,LI B,et al.Geological and isotopic constraints on the origin of the Anle carbonate-hosted Zn-Pb deposit in northwestern Yunnan Province,SW China[J].Ore Geol Rev,2016,74:88-100.
- [68]HU R Z,ZHOU M F.Multiple Mesozoic mineralization events in South China-an introduction to the thematic issue[J].Miner Deposita,2012,47(6):579-588.
- [69]胡瑞忠,陈伟,毕献武,等.扬子克拉通前寒武纪基底对中生代大面积低温成矿的制约[J].地学前缘,2020,27(2):137-150.
- [70]CAI J X,ZHANG K J.A new model for the Indochina and South China collision during the Late Permian to the Middle Triassic[J].Tectonophys,2008,467(1):35-43.
- [71]WANG C M,DENG J,CARRANZA E J M,et al.Nature,diversity and temporal-spatial distributions of sediment-hosted Pb-Zn deposits in China[J].Ore Geol Rev,2014,56:327-351.
- [72]HOGGARD M J,CZARNOTA K,RICHARDS F D,et al.Global distribution of sediment-hosted metals controlled by craton edge stability[J].Nature Geosci,2020,13(7):504-510.
- [73]钟宏,宋谢炎,黄智龙,等.近十年来中国矿床地球化学研究进展简述[J].矿物岩石地球化学通报,2021,40(04):819-844+1001.
- [74]LUO K,ZHOU J X,HUANG Z L,et al.New insights into the origin of early Cambrian carbonate hosted Pb-Zn deposits in South China:A case study of the Maliping Pb-Zn deposit[J].Gondwana Research,2019,70:88-103.